Literature DB >> 19449351

Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution.

Shenglai Yao1, Yun Xiong, Xinhao Zhang, Maria Schlangen, Helmut Schwarz, Carsten Milsmann, Matthias Driess.   

Abstract

Easy breakage to open-shells: The diamagnetic butterfly-like dichalcogen complexes 1 (E = Se) and 2 (E = Te) with a {Ni(II)(2)E(2)} core, undergo facile dissociation in solution via spin crossover to give the unprecedented mononuclear paramagnetic superselenide and supertelluride species 1' and 2', respectively, along with the nickel(I) fragment [LNi(I)]; R = 2,6-diisopropylphenyl.

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Year:  2009        PMID： 19449351     DOI： 10.1002/anie.200901132

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Conversion of E4 (E4 =P4 , As4 , AsP3 ) by Ni(0) and Ni(I) Synthons - A Comparative Study.

Authors:  Maria Haimerl; Christian Graßl; Michael Seidl; Martin Piesch; Manfred Scheer
Journal:  Chemistry       Date:  2021-11-23       Impact factor: 5.020

2.  Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides.

Authors:  Conrad A P Goodwin; Benjamin L L Réant; Gianni F Vettese; Jon G C Kragskow; Marcus J Giansiracusa; Ida M DiMucci; Kyle M Lancaster; David P Mills; Stephen Sproules
Journal:  Inorg Chem       Date:  2020-05-18       Impact factor: 5.165

3.  Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction.

Authors:  Nathaniel J Hartmann; Guang Wu; Trevor W Hayton
Journal:  Chem Sci       Date:  2018-06-27       Impact factor: 9.825
  3 in total

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