Literature DB >> 19449350

Controlled oligomerization of Lewis acid/base-stabilized phosphanylalanes.

Michael Bodensteiner1, Ulf Vogel, Alexey Y Timoshkin, Manfred Scheer.   

Abstract

PAls should stick together: The cyclo-trimer 2 is obtained by H(2) elimination of Lewis acid/base-stabilized parent compound of the phosphanylalanes 1. The elimination is controlled by fine tuning the temperature and solvent conditions. A subsequent H(2) elimination produces the ladder compound 3. Compounds 2 and 3 are the first of a new class of Group 13/15 compounds which show no additionally donor-acceptor bonds within the framework.

Entities:  

Year:  2009        PMID: 19449350     DOI: 10.1002/anie.200901064

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Monomeric β-Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH2 Groups (E=P, As).

Authors:  Bin Li; Susanne Bauer; Michael Seidl; Alexey Y Timoshkin; Manfred Scheer
Journal:  Chemistry       Date:  2019-10-04       Impact factor: 5.236

  2 in total

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