| Literature DB >> 19449350 |
Michael Bodensteiner1, Ulf Vogel, Alexey Y Timoshkin, Manfred Scheer.
Abstract
PAls should stick together: The cyclo-trimer 2 is obtained by H(2) elimination of Lewis acid/base-stabilized parent compound of the phosphanylalanes 1. The elimination is controlled by fine tuning the temperature and solvent conditions. A subsequent H(2) elimination produces the ladder compound 3. Compounds 2 and 3 are the first of a new class of Group 13/15 compounds which show no additionally donor-acceptor bonds within the framework.Entities:
Year: 2009 PMID: 19449350 DOI: 10.1002/anie.200901064
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336