Literature DB >> 19437518

A powerful chiral counteranion motif for asymmetric catalysis.

Pilar García-García1, Frank Lay, Patricia García-García, Constantinos Rabalakos, Benjamin List.   

Abstract

Room to swing a cat: A chiral disulfonimide has been designed as a powerful new motif for asymmetric catalysis. As a first illustration, a highly efficient and enantioselective Mukaiyama aldol reaction has been developed (see scheme). The actual catalyst is proposed to be an N-silyl imide which is generated in situ.

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Year:  2009        PMID： 19437518     DOI： 10.1002/anie.200901768

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  27 in total

1.  The progression of chiral anions from concepts to applications in asymmetric catalysis.

Authors:  Robert J Phipps; Gregory L Hamilton; F Dean Toste
Journal:  Nat Chem       Date:  2012-07-24       Impact factor: 24.427

2.  Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products.

Authors:  Emily C Gentry; Lydia J Rono; Martina E Hale; Rei Matsuura; Robert R Knowles
Journal:  J Am Chem Soc       Date:  2018-02-21       Impact factor: 15.419

3.  Chiral sulfinamide/achiral sulfonic acid cocatalyzed enantioselective protonation of enol silanes.

Authors:  Elizabeth M Beck; Alan M Hyde; Eric N Jacobsen
Journal:  Org Lett       Date:  2011-07-25       Impact factor: 6.005

4.  Acetylphosphonate as a surrogate of acetate or acetamide in organocatalyzed enantioselective aldol reactions.

Authors:  Jie Guang; Qunsheng Guo; John Cong-Gui Zhao
Journal:  Org Lett       Date:  2012-05-31       Impact factor: 6.005

5.  Gold(I)-catalyzed enantioselective synthesis of pyrazolidines, isoxazolidines, and tetrahydrooxazines.

Authors:  R L Lalonde; Z J Wang; M Mba; A D Lackner; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2010       Impact factor: 15.336

6.  Stereoselective synthesis of dienyl-carboxylate building blocks: formal synthesis of inthomycin C.

Authors:  Caroline Souris; Frédéric Frébault; Ashay Patel; Davide Audisio; K N Houk; Nuno Maulide
Journal:  Org Lett       Date:  2013-06-13       Impact factor: 6.005

7.  Catalytic Alkene Cyclization Reactions for the Stereoselective Synthesis of Complex "Terpenoid-like" Heterocycles.

Authors:  Jared T Moore; Cristian Soldi; James C Fettinger; Jared T Shaw
Journal:  Chem Sci       Date:  2012-10-25       Impact factor: 9.825

Review 8.  Asymmetric ion-pairing catalysis.

Authors:  Katrien Brak; Eric N Jacobsen
Journal:  Angew Chem Int Ed Engl       Date:  2012-11-28       Impact factor: 15.336

9.  Asymmetric additions to dienes catalysed by a dithiophosphoric acid.

Authors:  Nathan D Shapiro; Vivek Rauniyar; Gregory L Hamilton; Jeffrey Wu; F Dean Toste
Journal:  Nature       Date:  2011-02-10       Impact factor: 49.962

Review 10.  Rational design of dynamic ammonium salt catalysts towards more flexible and selective function.

Authors:  Kazuaki Ishihara
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2009       Impact factor: 3.493
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