Literature DB >> 19435344

An isolable NHC-supported silanone.

Yun Xiong1, Shenglai Yao, Matthias Driess.   

Abstract

The unique isolable silanone complex 3 has been synthesized and isolated in 94% yield by the remarkably facile oxygenation of the NHC-silylene precursor 2 featuring a Si(II) atom with unusually high nucleophilicity. The latter precursor is easily accessible by reaction of the stable silylene 1 with the corresponding N-heterocyclic carbene (NHC) at -60 degrees C. The remarkably short Si=O distance of 1.541(2) A in 3 suggests the presence of a betaine-like Si=O pi system with balanced electrostatics.

Entities:  

Year:  2009        PMID： 19435344     DOI： 10.1021/ja9031049

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  Main group chemistry: A heavier-element ketone at last.

Authors:  Philip P Power
Journal:  Nat Chem       Date:  2012-03-25       Impact factor: 24.427

2.  Stabilization of elusive silicon oxides.

Authors:  Yuzhong Wang; Mingwei Chen; Yaoming Xie; Pingrong Wei; Henry F Schaefer; Paul von R Schleyer; Gregory H Robinson
Journal:  Nat Chem       Date:  2015-04-20       Impact factor: 24.427

3.  NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: A facile synthesis of octaphenylcyclotetra(siloxane).

Authors:  Abigail Albright; Robert E Gawley
Journal:  Tetrahedron Lett       Date:  2011-11-16       Impact factor: 2.415

4.  From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.

Authors:  Yun Xiong; Shenglai Yao; Robert Müller; Martin Kaupp; Matthias Driess
Journal:  Nat Chem       Date:  2010-05-30       Impact factor: 24.427

5.  A stable germanone as the first isolated heavy ketone with a terminal oxygen atom.

Authors:  Liangchun Li; Tomohide Fukawa; Tsukasa Matsuo; Daisuke Hashizume; Hiroyuki Fueno; Kazuyoshi Tanaka; Kohei Tamao
Journal:  Nat Chem       Date:  2012-03-25       Impact factor: 24.427

6.  Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors:  Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Sci       Date:  2013-08-01       Impact factor: 9.825

Review 7.  Bonding and structure of disilenes and related unsaturated group-14 element compounds.

Authors:  Mitsuo Kira
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2012       Impact factor: 3.493

Review 8.  Acid-Base Free Main Group Carbonyl Analogues.

Authors:  Ying Kai Loh; Simon Aldridge
Journal:  Angew Chem Int Ed Engl       Date:  2020-10-19       Impact factor: 15.336

Review 9.  Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis.

Authors:  Hye Won Moon; Josep Cornella
Journal:  ACS Catal       Date:  2022-01-07       Impact factor: 13.084

10.  Distannabarrelenes with Three Coordinated SnII Atoms.

Authors:  Mahendra K Sharma; Timo Glodde; Beate Neumann; Hans-Georg Stammler; Rajendra S Ghadwal
Journal:  Chemistry       Date:  2020-07-28       Impact factor: 5.236
  10 in total

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