Literature DB >> 19434635

Discovery of heteroatom-"embedded" Te {W18O54} nanofunctional polyoxometalates by use of cryospray mass spectrometry.

Jun Yan1, De-Liang Long, Elizabeth F Wilson, Leroy Cronin.   

Abstract

The cryo game: Heteroatom-embedded nanofunctional clusters are described that incorporate a [Te(VI)O(6)](6-) species contained within a {W(18)O(54)} cage. Not only does the tellurium-based species activate the {W(18)O(54)} cluster surface for assembly of larger nanoscale structures, such as [H(10)Te(VI) (2)W(58)O(198)](26-), it also undergoes a redox transformation inside the cluster from [Te(VI)O(6)](6-) to [Te(IV)O(3)](2-).

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Year:  2009        PMID： 19434635     DOI： 10.1002/anie.200806343

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions.

Authors:  Irene Prat; Jennifer S Mathieson; Mireia Güell; Xavi Ribas; Josep M Luis; Leroy Cronin; Miquel Costas
Journal:  Nat Chem       Date:  2011-09-04       Impact factor: 24.427

2.  Catalysis of "outer-phase" oxygen atom exchange reactions by encapsulated "inner-phase" water in {V15Sb6}-type polyoxovanadates.

Authors:  Michael Wendt; Ulrike Warzok; Christian Näther; Jan van Leusen; Paul Kögerler; Christoph A Schalley; Wolfgang Bensch
Journal:  Chem Sci       Date:  2016-01-08       Impact factor: 9.825

3.  Ligand-Directed Template Assembly for the Construction of Gigantic Molybdenum Blue Wheels.

Authors:  Weimin Xuan; Robert Pow; Qi Zheng; Nancy Watfa; De-Liang Long; Leroy Cronin
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-28       Impact factor: 15.336

4.  Assembly of Lanthanide-Containing Tungstotellurates(VI): Syntheses, Structures, and Catalytic Properties.

Authors:  Jie Li; Shuxia Shang; Zhengguo Lin; Zishuo Yao; Ni Zhen; Zhen Li; Yingnan Chi; Changwen Hu
Journal:  Front Chem       Date:  2020-11-23       Impact factor: 5.221
  4 in total

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