| Literature DB >> 19425029 |
Min Wang1, Jian Gao, Pavel Müller, Bernd Giese.
Abstract
Caught on the hop: In multistep electron transfer (ET) reactions through peptides, aliphatic amino acids can also act as relay stations. With cysteine, the reaction occurs as a proton-coupled electron transfer (PCET) with water used as a mediator for the proton transfer (see picture).Entities:
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Year: 2009 PMID: 19425029 DOI: 10.1002/anie.200900827
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336