Literature DB >> 19425027

Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex.

Jamespandi Annaraj1, Jaeheung Cho, Yong-Min Lee, Sung Yeon Kim, Reza Latifi, Sam P de Visser, Wonwoo Nam.   

Abstract

The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on eta(2) fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X.

Entities:  

Mesh：

Substances：

Year:  2009        PMID： 19425027     DOI： 10.1002/anie.200900118

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  24 in total

1.  Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.

Authors:  Michael K Coggins; Santiago Toledo; Erika Shaffer; Werner Kaminsky; Jason Shearer; Julie A Kovacs
Journal:  Inorg Chem       Date:  2012-05-29       Impact factor: 5.165

Review 2.  Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes.

Authors:  Domenick F Leto; Timothy A Jackson
Journal:  J Biol Inorg Chem       Date:  2013-11-27       Impact factor: 3.358

3.  A MnII MnIII -Peroxide Complex Capable of Aldehyde Deformylation.

Authors:  Adriana M Magherusan; Subhasree Kal; Daniel N Nelis; Lorna M Doyle; Erik R Farquhar; Lawrence Que; Aidan R McDonald
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-27       Impact factor: 15.336

4.  Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexes.

Authors:  Michael K Coggins; Vlad Martin-Diaconescu; Serena DeBeer; Julie A Kovacs
Journal:  J Am Chem Soc       Date:  2013-03-12       Impact factor: 15.419

5.  Geometric and electronic structure of a peroxomanganese(III) complex supported by a scorpionate ligand.

Authors:  Hannah E Colmer; Robert A Geiger; Domenick F Leto; Gayan B Wijeratne; Victor W Day; Timothy A Jackson
Journal:  Dalton Trans       Date:  2014-10-14       Impact factor: 4.390

Review 6.  Cyanobacterial alkane biosynthesis further expands the catalytic repertoire of the ferritin-like 'di-iron-carboxylate' proteins.

Authors:  Carsten Krebs; J Martin Bollinger; Squire J Booker
Journal:  Curr Opin Chem Biol       Date:  2011-04       Impact factor: 8.822

Review 7.  Oxygen activation by mononuclear Mn, Co, and Ni centers in biology and synthetic complexes.

Authors:  Adam T Fiedler; Anne A Fischer
Journal:  J Biol Inorg Chem       Date:  2016-11-16       Impact factor: 3.358

8.  Mimicking Class I b Mn2 -Ribonucleotide Reductase: A MnII2 Complex and Its Reaction with Superoxide.

Authors:  Adriana M Magherusan; Ang Zhou; Erik R Farquhar; Max García-Melchor; Brendan Twamley; Lawrence Que; Aidan R McDonald
Journal:  Angew Chem Int Ed Engl       Date:  2017-12-27       Impact factor: 15.336

9.  Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.

Authors:  Michael K Coggins; Xianru Sun; Yeonju Kwak; Edward I Solomon; Elena Rybak-Akimova; Julie A Kovacs
Journal:  J Am Chem Soc       Date:  2013-04-03       Impact factor: 15.419

10.  An anionic N-donor ligand promotes manganese-catalyzed water oxidation.

Authors:  Karin J Young; Michael K Takase; Gary W Brudvig
Journal:  Inorg Chem       Date:  2013-06-18       Impact factor: 5.165
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.