| Literature DB >> 19421310 |
W Robert Scheidt1, Kristin E Buentello, Noelle Ehlinger, Arnaldo Cinquantini, Marco Fontani, Franco Laschi.
Abstract
The electrochemistry of [Cu(OEP)] and [Ni(OEP)] are compared with the mixed-valence π-cations [Cu(OEP•/2)]2+and[Ni(OEP•/2)]2+. These electrochemical studies, carried out with cyclic voltametry and hydrodynamic voltametry, show that the mixed valence π-cations have distinct electrochemical properties, although the differences between the [M(OEP)](+/0) and [M(OEP•/2)]2+/0 processes are subtle.Entities:
Year: 2008 PMID: 19421310 PMCID: PMC2405768 DOI: 10.1016/j.ica.2006.12.028
Source DB: PubMed Journal: Inorganica Chim Acta ISSN: 0020-1693 Impact factor: 2.545