Characterization and photocatalytic activity of poly(3-hexylthiophene)-modified TiO2 for degradation of methyl orange under visible light.

Poly(3-hexylthiophene) (P3HT) was synthesized via chemical oxidative polymerization with anhydrous FeCl(3) as oxidant, 3-hexylthiophene as monomer, chloroform as solvent. TiO(2) nanoparticles modified by a small amount of P3HT (TiO(2)/P3HT) were prepared by blending TiO(2) nanoparticles and P3HT in chloroform solution. The resulting photocatalysts were characterized by the methods of TEM, XRD, FT-IR, XPS and UV-vis diffuse reflectance spectroscope. The photocatalytic activity of TiO(2)/P3HT was investigated by degrading methyl orange under visible light. The degradation rate of methyl orange was 88.5 and 13.5% when it was degradated by TiO(2)/P3HT and neat TiO(2)(P-25) for 10h, respectively. In addition, TiO(2)/P3HT nanocomposites showed excellent photocatalytic stability after 10 cycles under visible light irradiation. A possible mechanism for the photocatalytic oxidative degradation was also discussed.