| Literature DB >> 19398332 |
Bala Kishan Gorityala1, Shuting Cai, Jimei Ma, Xue-Wei Liu.
Abstract
A mild and efficient synthesis of pseudoglycosides has been developed using metal free (S)-camphorsulfonic acid. (S)-CSA acts as an excellent catalyst for conversion of 2,4,6-tri-O-acetyl-D-glucal to 2,3-unsaturated O-glycosides. A wide range of biologically active natural products, alcohols and thiols could be coupled with glucal to give the desired pseudoglycosides in good to excellent yields with exclusive alpha-stereoselectivity.Entities:
Mesh：
Substances：
Year: 2009 PMID： 19398332 DOI： 10.1016/j.bmcl.2009.04.003
Source DB: PubMed Journal: Bioorg Med Chem Lett ISSN： 0960-894X Impact factor: 2.823