| Literature DB >> 19397325 |
Koushik Ghosh1, Jiming Hu, Henry S White, Peter J Stang.
Abstract
We present a general strategy for the synthesis of stable, multifunctional cuboctahedral complexes in which coordination-driven self-assembly allows for precise control over positioning of either ferrocene or crown ether functionalities. The appropriate stoichiometric combination of functionalized 120 degree diplatinum acceptor units with tritopic donor units afforded supramolecular cuboctahedra with covalently linked functional groups. The compounds are characterized by multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and electrochemistry.Entities:
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Year: 2009 PMID: 19397325 PMCID: PMC2775065 DOI: 10.1021/ja902045q
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419