Literature DB >> 19377688

Ambiphilic allenes: synthesis and reactivity.

David Tejedor1, Gabriela Méndez-Abt, Javier González-Platas, Miguel A Ramírez, Fernando García-Tellado.   

Abstract

Ambiphilic allenes are generated by an organocatalyzed domino reaction of alkyl propiolates and aromatic 1,2-diketones; in the absence of any external chemical agent, these allenes perform a thermally-driven dimerization reaction to generate the corresponding fully-substituted cyclobutanes in a regio- and highly stereoselective manner.

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Year:  2009        PMID: 19377688     DOI: 10.1039/b819613c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Formal [4+3] epoxide cascade reaction via a complementary ambiphilic pairing strategy.

Authors:  Alan Rolfe; Thiwanka B Samarakoon; Paul R Hanson
Journal:  Org Lett       Date:  2010-03-19       Impact factor: 6.005

  1 in total

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