Literature DB >> 19377683

Alkanes to carboxylic acids in aqueous medium: metal-free and metal-promoted highly efficient and mild conversions.

Marina V Kirillova1, Alexander M Kirillov, Maxim L Kuznetsov, José A L Silva, João J R Fraústo da Silva, Armando J L Pombeiro.   

Abstract

A convenient and clean route to transform, in aqueous medium, various alkanes to carboxylic acids via single-pot carboxylation with CO and water, under mild conditions, has been achieved, proceeding efficiently and selectively even without any metal catalyst and any acid additive, at low temperatures; the relevant hydroxylating role of H(2)O and radical mechanisms are disclosed by radical-trap, H(2)(18)O and DFT studies.

Entities:  

Year:  2009        PMID： 19377683     DOI： 10.1039/b900853e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Gold Nanoparticles Deposited on Surface Modified Carbon Xerogels as Reusable Catalysts for Cyclohexane C-H Activation in the Presence of CO and Water.

Authors:  Ana Paula da Costa Ribeiro; Luísa Margarida Dias Ribeiro de Sousa Martins; Sónia Alexandra Correia Carabineiro; José Luís Figueiredo; Armando José Latourrette Pombeiro
Journal:  Molecules       Date:  2017-04-09       Impact factor: 4.411

2.  Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison.

Authors:  Inês A S Matias; Ana P C Ribeiro; Luísa M D R S Martins
Journal:  Molecules       Date:  2020-11-30       Impact factor: 4.411

3.  Parallel affinity-based isolation of leukocyte subsets using microfluidics: application for stroke diagnosis.

Authors:  Swathi R Pullagurla; Małgorzata A Witek; Joshua M Jackson; Maria A M Lindell; Mateusz L Hupert; Irina V Nesterova; Alison E Baird; Steven A Soper
Journal:  Anal Chem       Date:  2014-04-01       Impact factor: 6.986

4.  A 3D MOF based on Adamantoid Tetracopper(II) and Aminophosphine Oxide Cages: Structural Features and Magnetic and Catalytic Properties.

Authors:  Ewelina I Śliwa; Dmytro S Nesterov; Marina V Kirillova; Julia Kłak; Alexander M Kirillov; Piotr Smoleński
Journal:  Inorg Chem       Date:  2021-06-13       Impact factor: 5.165

5.  Engineering of CYP153A33 With Enhanced Ratio of Hydroxylation to Overoxidation Activity in Whole-Cell Biotransformation of Medium-Chain 1-Alkanols.

Authors:  Hyuna Park; Doyeong Bak; Wooyoung Jeon; Minjung Jang; Jung-Oh Ahn; Kwon-Young Choi
Journal:  Front Bioeng Biotechnol       Date:  2022-01-03
  5 in total

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