Literature DB >> 19354327

One-pot o-nitrobenzenesulfonylhydrazide (NBSH) formation-diimide alkene reduction protocol.

Barrie J Marsh1, David R Carbery.   

Abstract

A one-pot protocol for the formation of 2-nitrobenzenesulfonylhydrazide (NBSH) from commercial reagents and subsequent alkene reduction is presented. The transformation is operationally simple and generally efficient for effecting diimide alkene reductions. A range of 16 substrates have been reduced, highlighting the unique chemoselectivity of diimide as a reduction system.

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Year:  2009        PMID: 19354327     DOI: 10.1021/jo900237y

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Arenophile-Mediated Dearomative Reduction.

Authors:  Mikiko Okumura; Stephanie M Nakamata Huynh; Jola Pospech; David Sarlah
Journal:  Angew Chem Int Ed Engl       Date:  2016-11-23       Impact factor: 15.336

2.  Synthetic Approach toward Enantiopure Cyclic Sulfinamides.

Authors:  Glebs Jersovs; Matiss Bojars; Pavel A Donets; Edgars Suna
Journal:  Org Lett       Date:  2022-06-16       Impact factor: 6.072

  2 in total

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