Literature DB >> 19350597

Reversible switching of the shear modulus of photoresponsive liquid-crystalline polymers.

Eric Verploegen1, Johannes Soulages, Mariel Kozberg, Tejia Zhang, Gareth McKinley, Paula Hammond.   

Abstract

Manipulation makes light work: The morphology and rheological properties of a liquid-crystalline system can be dynamically manipulated with UV light by attaching photoresponsive liquid-crystalline moieties to a siloxane-based polymer. Stimulation with UV light induces a conformational change in the molecule, which disrupts the liquid-crystalline mesophase (see picture), and results in a dramatic change in its rheological properties.

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Year:  2009        PMID: 19350597      PMCID: PMC3387558          DOI: 10.1002/anie.200900583

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  13 in total

1.  A new opto-mechanical effect in solids.

Authors:  H Finkelmann; E Nishikawa; G G Pereira; M Warner
Journal:  Phys Rev Lett       Date:  2001-06-15       Impact factor: 9.161

2.  Artificial muscles based on liquid crystal elastomers.

Authors:  Min-Hui Li; Patrick Keller
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2006-10-15       Impact factor: 4.226

3.  Soft actuators based on liquid-crystalline elastomers.

Authors:  Yanlei Yu; Tomiki Ikeda
Journal:  Angew Chem Int Ed Engl       Date:  2006-08-18       Impact factor: 15.336

4.  Suspended heated silicon platform for rapid thermal control of surface reactions with application to carbon nanotube synthesis.

Authors:  Lucas van Laake; Anastasios John Hart; Alexander H Slocum
Journal:  Rev Sci Instrum       Date:  2007-08       Impact factor: 1.523

Review 5.  Photomechanics of liquid-crystalline elastomers and other polymers.

Authors:  Tomiki Ikeda; Jun-ichi Mamiya; Yanlei Yu
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

6.  A simple class of photorheological fluids: surfactant solutions with viscosity tunable by light.

Authors:  Aimee M Ketner; Rakesh Kumar; Tanner S Davies; Patrick W Elder; Srinivasa R Raghavan
Journal:  J Am Chem Soc       Date:  2007-01-23       Impact factor: 15.419

7.  Giant lateral electrostriction in ferroelectric liquid-crystalline elastomers.

Authors:  W Lehmann; H Skupin; C Tolksdorf; E Gebhard; R Zentel; P Krüger; M Lösche; F Kremer
Journal:  Nature       Date:  2001-03-22       Impact factor: 49.962

8.  Shape memory effect exhibited by smectic-C liquid crystalline elastomers.

Authors:  Ingrid A Rousseau; Patrick T Mather
Journal:  J Am Chem Soc       Date:  2003-12-17       Impact factor: 15.419

9.  Fast liquid-crystal elastomer swims into the dark.

Authors:  Miguel Camacho-Lopez; Heino Finkelmann; Peter Palffy-Muhoray; Michael Shelley
Journal:  Nat Mater       Date:  2004-04-25       Impact factor: 43.841

10.  Photomechanics: directed bending of a polymer film by light.

Authors:  Yanlei Yu; Makoto Nakano; Tomiki Ikeda
Journal:  Nature       Date:  2003-09-11       Impact factor: 49.962

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  2 in total

1.  Photoinduced viscosity control of lecithin-based reverse wormlike micellar systems using azobenzene derivatives.

Authors:  Masaaki Akamatsu; Mayu Shiina; Rekha Goswami Shrestha; Kenichi Sakai; Masahiko Abe; Hideki Sakai
Journal:  RSC Adv       Date:  2018-06-29       Impact factor: 3.361

2.  Reversibly tuning hydrogel stiffness through photocontrolled dynamic covalent crosslinks.

Authors:  Joseph V Accardo; Julia A Kalow
Journal:  Chem Sci       Date:  2018-06-19       Impact factor: 9.825

  2 in total

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