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Literature DB >> 19348485

[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)]: a molecular polyphosphide of the rare-earth elements.

Sergey N Konchenko¹, Nikolay A Pushkarevsky, Michael T Gamer, Ralf Köppe, Hansgeorg Schnöckel, Peter W Roesky.

Abstract

[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)], a molecular polyphosphide of the rare-earth elements having a realgar core structure, was synthesized by a one-electron redox reaction of divalent samarocen and white phosphorus.

Entities: Chemical

Year: 2009 PMID： 19348485 DOI： 10.1021/ja901045m

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

8 in total

1. An actinide Zintl cluster: a tris(triamidouranium)μ3-η2:η2:η2-heptaphosphanortricyclane and its diverse synthetic utility.

Authors: Dipti Patel; Floriana Tuna; Eric J L McInnes; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Angew Chem Int Ed Engl Date: 2013-10-14 Impact factor: 15.336

2. Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds.

Authors: Clément Camp; Laurent Maron; Robert G Bergman; John Arnold
Journal: J Am Chem Soc Date: 2014-12-03 Impact factor: 15.419

[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)]: a molecular polyphosphide of the rare-earth elements.

1. An actinide Zintl cluster: a tris(triamidouranium)μ3-η2:η2:η2-heptaphosphanortricyclane and its diverse synthetic utility.

2. Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds.

3. Influence of the nacnac Ligand in Iron(I)-Mediated P4 Transformations.

4. An Inverted-Sandwich Diuranium μ-η⁵:η⁵-Cyclo-P₅ Complex Supported by U-P₅ δ-Bonding.

5. The approach to 4d/4f-polyphosphides.

6. Transformations of the cyclo-P₄ ligand in [Cp'''Co(η⁴-P₄)].

7. An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P5 Complex Supported by U-P5 δ-Bonding.

8. Insertion of Phosphenium Ions into a Bicyclo[1.1.0]Tetraphosphabutane Iron Complex.