| Literature DB >> 19344131 |
Hai-Bo Yang1, Brian H Northrop, Yao-Rong Zheng, Koushik Ghosh, Matthew M Lyndon, David C Muddiman, Peter J Stang.
Abstract
A new class of 120 degrees dendritic di-Pt(II) acceptor subunits has been designed and synthesized, from which six-component hexagonal metallodendrimers were easily formed with 120 degrees dendritic dipyridine donors via [3 + 3] coordination-driven self-assembly. The structures of all metallodendrimers are confirmed by multinuclear NMR, ESI-TOF-MS/ESI-FTMS, and elemental analysis. MMFF force-field simulations indicates that all metallodendrimers have a hexagonal ring with an internal radius of approximately 1.4 nm.Entities:
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Year: 2009 PMID: 19344131 PMCID: PMC2674761 DOI: 10.1021/jo900067v
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354