Literature DB >> 19343238

The selective catalytic formation of beta-boryl aldehydes through a base-free approach.

Amadeu Bonet1, Vanesa Lillo, Jesús Ramírez, M Mar Díaz-Requejo, Elena Fernández.   

Abstract

(NHC)Cu(I) complexes are key in a new strategy to selectively add a boron unit at the beta-position of alpha,beta-unsaturated aldehydes in the absence of a base.

Entities:  

Year:  2009        PMID： 19343238     DOI： 10.1039/b901767d

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  1 in total

1.  Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.

Authors:  Hao Wu; Suttipol Radomkit; Jeannette M O'Brien; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2012-05-04       Impact factor: 15.419
  1 in total

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