Literature DB >> 19343084

Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation.

Guido D Frey1, Rian D Dewhurst, Shazia Kousar, Bruno Donnadieu, Guy Bertrand.   

Abstract

A series of mono- and dicarbene gold(I) complexes of types Au(CAAC)(Cl) [CAAC = cyclic (alkyl)(amino)carbene] (1) and [Au(CAAC)(2)](+)[X](-) (X = Cl, AuCl(2)) (2) have been prepared through reaction of AuCl(SMe(2)) with free carbenes a-e, and structurally characterized by single X-ray diffraction studies (1a, 1b, 2d, 2e). In addition two new free cyclic (alkyl)(amino)carbenes (c and e) have been synthesized.

Entities:  

Year:  2008        PMID： 19343084      PMCID： PMC2394856          DOI： 10.1016/j.jorganchem.2008.01.026

Source DB:  PubMed          Journal:  J Organomet Chem        ISSN： 0022-328X            Impact factor:   2.369


  21 in total

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Authors:  Vincent Lavallo; Yves Canac; Bruno Donnadieu; Wolfgang W Schoeller; Guy Bertrand
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6.  Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts.

Authors:  Rodolphe Jazzar; Jean-Baptiste Bourg; Rian D Dewhurst; Bruno Donnadieu; Guy Bertrand
Journal:  J Org Chem       Date:  2007-04-05       Impact factor: 4.354

7.  N-heterocyclic carbenes: a new concept in organometallic catalysis.

Authors:  Wolfgang A Herrmann
Journal:  Angew Chem Int Ed Engl       Date:  2002-04-15       Impact factor: 15.336

8.  Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.

Authors:  Guido D Frey; Vincent Lavallo; Bruno Donnadieu; Wolfgang W Schoeller; Guy Bertrand
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9.  Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.

Authors:  Vincent Lavallo; Guido D Frey; Shazia Kousar; Bruno Donnadieu; Guy Bertrand
Journal:  Proc Natl Acad Sci U S A       Date:  2007-08-13       Impact factor: 11.205

10.  Preparation of Au(I), Ag(I), and Pd(II) N-heterocyclic carbene complexes utilizing a methylpyridyl-substituted NHC ligand. formation of a luminescent coordination polymer.

Authors:  Vincent J Catalano; Anthony O Etogo
Journal:  Inorg Chem       Date:  2007-06-05       Impact factor: 5.165
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  13 in total

1.  Homogeneous catalytic hydroamination of alkynes and allenes with ammonia.

Authors:  Vincent Lavallo; Guido D Frey; Bruno Donnadieu; Michele Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

2.  Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes with Arylamines.

Authors:  Alethea N Duncan; Ross A Widenhoefer
Journal:  Synlett       Date:  2010-02       Impact factor: 2.454

Review 3.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

Review 4.  Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.

Authors:  Saroj Kumar Kushvaha; Ankush Mishra; Herbert W Roesky; Kartik Chandra Mondal
Journal:  Chem Asian J       Date:  2022-02-26

5.  Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes.

Authors:  Xiaoming Zeng; Rei Kinjo; Bruno Donnadieu; Guy Bertrand
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6.  A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine.

Authors:  Xiaoming Zeng; Guido D Frey; Shazia Kousar; Guy Bertrand
Journal:  Chemistry       Date:  2009       Impact factor: 5.236

7.  Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.

Authors:  Xiaoming Zeng; Michele Soleilhavoup; Guy Bertrand
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8.  Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives.

Authors:  Xiaoming Zeng; Guido D Frey; Rei Kinjo; Bruno Donnadieu; Guy Bertrand
Journal:  J Am Chem Soc       Date:  2009-06-24       Impact factor: 15.419

9.  Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED.

Authors:  Alexander S Romanov; Saul T E Jones; Qinying Gu; Patrick J Conaghan; Bluebell H Drummond; Jiale Feng; Florian Chotard; Leonardo Buizza; Morgan Foley; Mikko Linnolahti; Dan Credgington; Manfred Bochmann
Journal:  Chem Sci       Date:  2019-11-13       Impact factor: 9.825

10.  Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.

Authors:  Ruth Dorel; Antonio M Echavarren
Journal:  Chem Rev       Date:  2015-04-06       Impact factor: 60.622
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