Literature DB >> 19322861

Formation of ammonia from an iron nitrido complex.

Jeremiah J Scepaniak1, Jessica A Young, Ranko P Bontchev, Jeremy M Smith.   

Abstract

Radical ideas: Reaction of the iron(IV) nitrido complex [PhB(MesIm)(3)Fe[triple chemical bond]N] (see picture, Mes=2,4,6-Me(3)C(6)H(2)) with TEMPO-H (1-hydroxy-2,2,6,6-tetramethylpiperidine) results in high yields of ammonia and quantitative formation of [PhB(MesIm)(3)Fe(tempo)]. The mechanism likely involves hydrogen-atom transfer from TEMPO-H to the nitrido complex. Similar reaction with the triphenylmethyl radical yields [PhB(MesIm)(3)Fe[triple chemical bond]N--CPh(3)].

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Year:  2009        PMID： 19322861     DOI： 10.1002/anie.200900381

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  33 in total

1.  High-Spin Iron Imido Complexes Competent for C-H Bond Amination.

Authors:  Matthew J T Wilding; Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2017-08-18       Impact factor: 15.419

2.  Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride.

Authors:  Robert K Thomson; Thibault Cantat; Brian L Scott; David E Morris; Enrique R Batista; Jaqueline L Kiplinger
Journal:  Nat Chem       Date:  2010-07-11       Impact factor: 24.427

3.  Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry.

Authors:  Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2016-02-04       Impact factor: 15.419

Review 4.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

5.  Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C-H Amination Efficacy.

Authors:  Yunjung Baek; Elisabeth T Hennessy; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2019-10-10       Impact factor: 15.419

6.  Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.

Authors:  John S Anderson; George E Cutsail; Jonathan Rittle; Bridget A Connor; William A Gunderson; Limei Zhang; Brian M Hoffman; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2015-06-10       Impact factor: 15.419

7.  M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

Authors:  Caroline T Saouma; Jonas C Peters
Journal:  Coord Chem Rev       Date:  2011-04       Impact factor: 22.315

8.  Styrene Aziridination by Iron(IV) Nitrides.

Authors:  Salvador B Muñoz; Wei-Tsung Lee; Diane A Dickie; Jeremiah J Scepaniak; Deepak Subedi; Maren Pink; Michael D Johnson; Jeremy M Smith
Journal:  Angew Chem Int Ed Engl       Date:  2015-07-15       Impact factor: 15.336

9.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

10.  Conversion of Fe-NH2 to Fe-N2 with release of NH3.

Authors:  John S Anderson; Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419
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