Literature DB >> 19322479

The influence of tetrahydrofuran on the structures and reactivities of lithium organo-amidocuprates.

Roberta Bomparola1, Robert P Davies, Stefan Hornauer, Andrew J P White.   

Abstract

The organo-amidocuprate [Cu(2)Li(2)Mes(2)(N(CH(2)Ph)(2))(2)] is solvated by thf to yield the monomeric contact ion pair complex [MesCuN(CH(2)Ph)(2).Li(thf)(3)] in which the Li cation is bound to the amido nitrogen; this behaviour differs significantly from that observed in diorganocuprates which favour solvent separate ion pairs.

Entities:  

Year:  2008        PMID: 19322479     DOI: 10.1039/b821206f

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Structural effects in lithiocuprate chemistry: the elucidation of reactive pentametallic complexes.

Authors:  Philip J Harford; Andrew J Peel; Joseph P Taylor; Shinsuke Komagawa; Paul R Raithby; Thomas P Robinson; Masanobu Uchiyama; Andrew E H Wheatley
Journal:  Chemistry       Date:  2014-02-19       Impact factor: 5.236

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.