Literature DB >> 19319442

Aromatic trifluoromethylation catalytic in copper.

Masahiro Oishi1, Hideaki Kondo, Hideki Amii.   

Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Entities:  

Year:  2009        PMID： 19319442     DOI： 10.1039/b823249k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  36 in total

1.  Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.

Authors:  Nicholas D Ball; J Brannon Gary; Yingda Ye; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2011-04-22       Impact factor: 15.419

2.  Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

Authors:  Yingda Ye; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2012-05-24       Impact factor: 15.419

3.  Investigations into Transition Metal Catalyzed Arene Trifluoromethylation Reactions.

Authors:  Yingda Ye; Melanie S Sanford
Journal:  Synlett       Date:  2012-09-01       Impact factor: 2.454

4.  Metallaphotoredox Perfluoroalkylation of Organobromides.

Authors:  Xiangbo Zhao; David W C MacMillan
Journal:  J Am Chem Soc       Date:  2020-11-09       Impact factor: 15.419

Review 5.  Catalysis for fluorination and trifluoromethylation.

Authors:  Takeru Furuya; Adam S Kamlet; Tobias Ritter
Journal:  Nature       Date:  2011-05-26       Impact factor: 49.962

6.  A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.

Authors:  Hiroyuki Morimoto; Tetsu Tsubogo; Nichole D Litvinas; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-25       Impact factor: 15.336

7.  The palladium-catalyzed trifluoromethylation of aryl chlorides.

Authors:  Eun Jin Cho; Todd D Senecal; Tom Kinzel; Yong Zhang; Donald A Watson; Stephen L Buchwald
Journal:  Science       Date:  2010-06-25       Impact factor: 47.728

8.  Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling.

Authors:  Todd D Senecal; Andrew T Parsons; Stephen L Buchwald
Journal:  J Org Chem       Date:  2011-01-14       Impact factor: 4.354

9.  Ligand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.

Authors:  Brett R Ambler; Santosh Peddi; Ryan A Altman
Journal:  Org Lett       Date:  2015-04-24       Impact factor: 6.005

10.  Study of the gas-phase intramolecular aryltrifluoromethylation of phenyl(trifluoromethyl)iodonium by ESI-MS/MS.

Authors:  Hao-Yang Wang; Zhang Xiang; Guo-Sheng Liu; Yin-Long Guo
Journal:  J Am Soc Mass Spectrom       Date:  2013-03-12       Impact factor: 3.109
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