Literature DB >> 19319420

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand.

Pawel Horeglad1, Grégory Nocton, Yaroslav Filinchuk, Jacques Pécaut, Marinella Mazzanti.   

Abstract

A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO(2)Py(5)][KI(2)Py(2)]}(n), and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

Entities:  

Year:  2009        PMID： 19319420     DOI： 10.1039/b821398d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  A uranium-based UO2(+)-Mn2+ single-chain magnet assembled trough cation-cation interactions.

Authors:  Victor Mougel; Lucile Chatelain; Johannes Hermle; Roberto Caciuffo; Eric Colineau; Floriana Tuna; Nicola Magnani; Arnaud de Geyer; Jacques Pécaut; Marinella Mazzanti
Journal:  Angew Chem Int Ed Engl       Date:  2013-12-06       Impact factor: 15.336

2.  The effect of iron binding on uranyl(v) stability.

Authors:  Radmila Faizova; Sarah White; Rosario Scopelliti; Marinella Mazzanti
Journal:  Chem Sci       Date:  2018-08-14       Impact factor: 9.825
  2 in total

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