Literature DB >> 19309087

Syntheses and structures of phenyl-C81-butyric acid methyl esters (PCBMs) from M3N@C80.

Chunying Shu1, Wei Xu, Carla Slebodnick, Hunter Champion, Wujun Fu, Jonathan E Reid, Hugo Azurmendi, Chunru Wang, Kim Harich, Harry C Dorn, Harry W Gibson.   

Abstract

Two new 6,6-open phenyl-C(81)-butyric acid methyl ester metallofulleroids, M(3)N@C(80)PCBM (M = Sc, Y), were synthesized by diazoalkane addition reactions and fully characterized. The results demonstrate that the reactive sites are the same for M(3)N@C(80) (M = Sc, Y) but dramatically different from that of C(60).

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Year:  2009        PMID: 19309087     DOI: 10.1021/ol9002527

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Sc3N@Ih -C80 as a novel Lewis acid to trap abnormal N-heterocyclic carbenes: the unprecedented formation of a singly bonded [6,6,6]-adduct.

Authors:  Muqing Chen; Lipiao Bao; Min Ai; Wangqiang Shen; Xing Lu
Journal:  Chem Sci       Date:  2015-12-02       Impact factor: 9.825

  1 in total

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