Literature DB >> 19301342

Closed and open clamlike structures formed by hydrogen-bonded pairs of cyclotricatechylene anions that contain cationic "meat".

Brendan F Abrahams1, Nicholas J Fitzgerald, Timothy A Hudson, Richard Robson, Tom Waters.   

Abstract

Clamming up: The hexaphenolic compound cyclotricatechylene, which has a bowl-shaped cavity, forms clamlike pairs that encapsulate cations (see picture). Variable hydrogen bonding allows two linked cyclotricatechylene clamshells to be in a closed arrangement when smaller cations such Rb(+) or Cs(+) provide the clam meat, whereas larger cations such as NMe(4) (+) and NEt(4) (+) cause the clam to be partially opened.

Entities:  

Year:  2009        PMID: 19301342     DOI: 10.1002/anie.200805789

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Syntheses of cyclotriveratrylene analogues and their long elusive triketone congeners.

Authors:  Nathan E Wright; Adel M ElSohly; Scott A Snyder
Journal:  Org Lett       Date:  2014-07-02       Impact factor: 6.005

2.  Spontaneous chiral resolution directed by symmetry restriction and π-π interaction.

Authors:  Jin-Tao Yu; Yan-Yan Shi; Junliang Sun; Jianhua Lin; Zhi-Tang Huang; Qi-Yu Zheng
Journal:  Sci Rep       Date:  2013-10-15       Impact factor: 4.379

  2 in total

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