| Literature DB >> 19301342 |
Brendan F Abrahams1, Nicholas J Fitzgerald, Timothy A Hudson, Richard Robson, Tom Waters.
Abstract
Clamming up: The hexaphenolic compound cyclotricatechylene, which has a bowl-shaped cavity, forms clamlike pairs that encapsulate cations (see picture). Variable hydrogen bonding allows two linked cyclotricatechylene clamshells to be in a closed arrangement when smaller cations such Rb(+) or Cs(+) provide the clam meat, whereas larger cations such as NMe(4) (+) and NEt(4) (+) cause the clam to be partially opened.Entities:
Year: 2009 PMID: 19301342 DOI: 10.1002/anie.200805789
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336