Literature DB >> 19294719

A dimeric magnesium(I) compound as a facile two-center/two-electron reductant.

Simon J Bonyhady1, Shaun P Green, Cameron Jones, Sharanappa Nembenna, Andreas Stasch.   

Abstract

The odd couple: A dimeric magnesium(I) complex acts as a facile and selective two-center/two-electron reductant towards a series of unsaturated substrates (see scheme; Ar = 2,6-iPr(2)C(6)H(3), Ad = 1-adamantyl). The novel reduced or reductively coupled products obtained from these reductions suggest that magnesium(I) compounds may find wide use in organic and organometallic syntheses.

Entities:  

Year:  2009        PMID： 19294719     DOI： 10.1002/anie.200900331

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

2.  Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer.

Authors:  Simon J Bonyhady; David Collis; Gernot Frenking; Nicole Holzmann; Cameron Jones; Andreas Stasch
Journal:  Nat Chem       Date:  2010-08-01       Impact factor: 24.427

3.  Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution.

Authors:  Clare Bakewell; Andrew J P White; Mark R Crimmin
Journal:  J Am Chem Soc       Date:  2016-09-22       Impact factor: 15.419

4.  Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters.

Authors:  Marina Perez-Jimenez; Natalia Curado; Celia Maya; Jesus Campos; Jesus Jover; Santiago Alvarez; Ernesto Carmona
Journal:  J Am Chem Soc       Date:  2021-03-23       Impact factor: 16.383

5.  Heteroleptic actinocenes: a thorium(iv)-cyclobutadienyl-cyclooctatetraenyl-di-potassium-cyclooctatetraenyl complex.

Authors:  Josef T Boronski; Ashley J Wooles; Stephen T Liddle
Journal:  Chem Sci       Date:  2020-06-10       Impact factor: 9.825

6.  Reactions of Fluoroalkanes with Mg-Mg Bonds: Scope, sp3 C-F/sp2 C-F Coupling and Mechanism.

Authors:  Greg Coates; Bryan J Ward; Clare Bakewell; Andrew J P White; Mark R Crimmin
Journal:  Chemistry       Date:  2018-10-05       Impact factor: 5.236
  6 in total

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