Literature DB >> 19294718

Gas-phase synthesis and reactivity of the lithium acetate enolate anion, -CH2CO2Li.

Matthew M Meyer1, George N Khairallah, Steven R Kass, Richard A J O'Hair.   

Abstract

Aerial pingpong: The lithium acetate enolate anion, the prototypical lithium salt of an alpha-deprotonated carboxylate, was prepared in the gas phase by electrospray ionization (ESI) and collision-induced ionization (CID). Its structure, reactivity, and energetics are presented along with the results of high-level computations.

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Year:  2009        PMID： 19294718     DOI： 10.1002/anie.200900245

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

Authors:  Mei Lu; Yijin Su; Pengyi Zhao; Xiaohan Ye; Yi Cai; Xiaodong Shi; Eric Masson; Fengyao Li; J Larry Campbell; Hao Chen
Journal:  Chemistry       Date:  2018-01-17       Impact factor: 5.236

2.  Gas Phase Reactions of Ions Derived from Anionic Uranyl Formate and Uranyl Acetate Complexes.

Authors:  Evan Perez; Cassandra Hanley; Stephen Koehler; Jordan Pestok; Nevo Polonsky; Michael Van Stipdonk
Journal:  J Am Soc Mass Spectrom       Date:  2016-09-07       Impact factor: 3.109

3.  Detection of Fleeting Amine Radical Cations and Elucidation of Chain Processes in Visible-Light-Mediated [3 + 2] Annulation by Online Mass Spectrometric Techniques.

Authors:  Yi Cai; Jiang Wang; Yuexiang Zhang; Zhi Li; David Hu; Nan Zheng; Hao Chen
Journal:  J Am Chem Soc       Date:  2017-08-25       Impact factor: 15.419

4.  Electrocatalytic redox neutral [3 + 2] annulation of N-cyclopropylanilines and alkenes.

Authors:  Qi Wang; Qile Wang; Yuexiang Zhang; Yasmine M Mohamed; Carlos Pacheco; Nan Zheng; Richard N Zare; Hao Chen
Journal:  Chem Sci       Date:  2020-11-09       Impact factor: 9.825
  4 in total

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