| Literature DB >> 19294711 |
Masaaki Ohba1, Ko Yoneda, Gloria Agustí, M Carmen Muñoz, Ana B Gaspar, José A Real, Mikio Yamasaki, Hideo Ando, Yoshihide Nakao, Shigeyoshi Sakaki, Susumu Kitagawa.
Abstract
The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)(4)]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional magnetic chemo-switching is achieved at room temperature. In situ magnetic measurements following guest vapor injection show that most guest molecules transform 1 from the low-spin (LS) state to the high-spin (HS) state, whereas CS(2) uniquely causes the reverse HS-to-LS transition.Entities:
Year: 2009 PMID: 19294711 DOI: 10.1002/anie.200806039
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336