Literature DB >> 19294710

Synthesis of orthorhombic Mo-V-Sb oxide species by assembly of pentagonal Mo6O21 polyoxometalate building blocks.

Masahiro Sadakane1, Keiko Yamagata, Katsunori Kodato, Keisuke Endo, Koshiro Toriumi, Yoshiki Ozawa, Tomoji Ozeki, Takuro Nagai, Yoshio Matsui, Norihito Sakaguchi, William D Pyrz, Douglas J Buttrey, Douglas A Blom, Thomas Vogt, Wataru Ueda.   

Abstract

Mix and match: The pentagonal [Mo(6)O(21)](n-) polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound.

Entities:  

Year:  2009        PMID： 19294710     DOI： 10.1002/anie.200805792

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Atomic-level imaging of Mo-V-O complex oxide phase intergrowth, grain boundaries, and defects using HAADF-STEM.

Authors:  William D Pyrz; Douglas A Blom; Masahiro Sadakane; Katsunori Kodato; Wataru Ueda; Thomas Vogt; Douglas J Buttrey
Journal:  Proc Natl Acad Sci U S A       Date:  2010-03-22       Impact factor: 11.205

2.  The evolution of the M1 local structure during preparation of VMoNbTeO catalysts for ethane oxidative dehydrogenation to ethylene.

Authors:  T Yu Kardash; E V Lazareva; D A Svintsitskiy; A V Ishchenko; V M Bondareva; R B Neder
Journal:  RSC Adv       Date:  2018-10-22       Impact factor: 4.036

3.  A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides.

Authors:  Simon Greiner; Jan Hettig; Alec Laws; Katharina Baumgärtner; Jenna Bustos; Ann-Christin Pöppler; Adam H Clark; May Nyman; Carsten Streb; Montaha Anjass
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-17       Impact factor: 16.823

4.  Giant Spherical Cluster with I-C140 Fullerene Topology.

Authors:  Sebastian Heinl; Eugenia Peresypkina; Jörg Sutter; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-28       Impact factor: 15.336

5.  Multi-slice frozen phonon simulations of high-angle annular dark field scanning transmission electron microscopy images of the structurally and compositionally complex Mo-V-Nb-Te oxide catalyst.

Authors:  Douglas A Blom; Thomas Vogt
Journal:  Adv Struct Chem Imaging       Date:  2018-07-31
  5 in total

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