Literature DB >> 19294287

Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates.

Ryan E Cowley1, Nathan A Eckert, Jérôme Elhaïk, Patrick L Holland.   

Abstract

The metastable iron(III) imido species LtBuFeNAd catalyzes transfer of the nitrene fragment NAd from an organic azide to isocyanides or CO, forming unsymmetrical carbodiimides or isocyanates.

Entities:  

Year:  2009        PMID： 19294287     DOI： 10.1039/b820620a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  High-Spin Iron Imido Complexes Competent for C-H Bond Amination.

Authors:  Matthew J T Wilding; Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2017-08-18       Impact factor: 15.419

2.  Access to well-defined ruthenium(I) and osmium(I) metalloradicals.

Authors:  Ayumi Takaoka; Laura C H Gerber; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2010-06-01       Impact factor: 15.336

3.  Intramolecular Fe(II)-catalyzed N-O or N-N bond formation from aryl azides.

Authors:  Benjamin J Stokes; Carl V Vogel; Linda K Urnezis; Minjie Pan; Tom G Driver
Journal:  Org Lett       Date:  2010-06-18       Impact factor: 6.005

4.  N2 functionalization at iron metallaboratranes.

Authors:  Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-10-21       Impact factor: 15.419

5.  Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactions.

Authors:  David E Herbert; Nadia C Lara; Theodor Agapie
Journal:  Chemistry       Date:  2013-10-14       Impact factor: 5.236

6.  M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

Authors:  Caroline T Saouma; Jonas C Peters
Journal:  Coord Chem Rev       Date:  2011-04       Impact factor: 22.315

7.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

8.  Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II).

Authors:  Megan E Reesbeck; Katarzyna Grubel; Daniel Kim; William W Brennessel; Brandon Q Mercado; Patrick L Holland
Journal:  Inorg Chem       Date:  2017-01-09       Impact factor: 5.165

9.  Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes.

Authors:  Sarina M Bellows; William W Brennessel; Patrick L Holland
Journal:  Eur J Inorg Chem       Date:  2016-05-30       Impact factor: 2.524

10.  Carbon-hydrogen bond activation, C-N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand.

Authors:  Daniel J Mindiola; Rory Waterman; Vlad M Iluc; Thomas R Cundari; Gregory L Hillhouse
Journal:  Inorg Chem       Date:  2014-12-01       Impact factor: 5.165
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