Literature DB >> 19294264

Formation of a new class of 7pi radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2.

Ruth Edge1, Robert J Less, Eric J L McInnes, Kristine Müther, Vesal Naseri, Jeremy M Rawson, Dominic S Wright.   

Abstract

The 2c-2e- P-P bonded dimers [(CH)2(NR)2P]2 dissociate in solution to give the persistent new 7pi radicals [(CH)2(NR)2P]*, which are isoelectronic with the well known S/N thiazolyl radicals.

Entities:  

Year:  2009        PMID： 19294264     DOI： 10.1039/b821241d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Stability of Carbocyclic Phosphinyl Radicals: Effect of Ring Size, Delocalization, and Sterics.

Authors:  Anna Ott; Péter R Nagy; Zoltán Benkő
Journal:  Inorg Chem       Date:  2022-10-04       Impact factor: 5.436

2.  Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation.

Authors:  Stefan Isenberg; Stefan Weller; Denis Kargin; Srećko Valić; Brigitte Schwederski; Zsolt Kelemen; Clemens Bruhn; Kristijan Krekić; Martin Maurer; Christoph M Feil; Martin Nieger; Dietrich Gudat; László Nyulászi; Rudolf Pietschnig
Journal:  ChemistryOpen       Date:  2019-06-26       Impact factor: 2.911

3.  1,3,2-Diazaphospholene-Catalyzed Reductive Cyclizations of Organohalides.

Authors:  Johannes Klett; Łukasz Woźniak; Nicolai Cramer
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-06       Impact factor: 16.823

4.  Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications.

Authors:  Jingjing Zhang; Jin-Dong Yang; Jin-Pei Cheng
Journal:  Chem Sci       Date:  2020-03-05       Impact factor: 9.825
  4 in total

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