Literature DB >> 19291721

Torsional photoisomerization proceeding adiabatically through a volume-conserving pathway in uninhibited fluid media.

Ioanna Balomenou1, George Pistolis.   

Abstract

Doing the hula twist? A photochemically stimulated inversion of an sp(2)-hybridized oxygen atom upon simultaneous rotation of two adjacent bonds may be possible in a pure singlet excited potential energy surface in uninhibited fluid media (see scheme).

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Year:  2009        PMID: 19291721     DOI: 10.1002/chem.200900306

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  1 in total

1.  Direct evidence for hula twist and single-bond rotation photoproducts.

Authors:  Aaron Gerwien; Monika Schildhauer; Stefan Thumser; Peter Mayer; Henry Dube
Journal:  Nat Commun       Date:  2018-06-28       Impact factor: 14.919

  1 in total

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