Literature DB >> 19278246

A broadly applicable mild method for the synthesis of gem-diperoxides from corresponding ketones or 1,3-dioxolanes.

Yun Li1, Hong-Dong Hao, Qi Zhang, Yikang Wu.   

Abstract

Ketones or ketals were readily converted into the corresponding gem-dihydroperoxides in high yields by treatment with ethereal H(2)O(2) at ambient temperature in the presence of 2-5 mol % of phosphomolybdic acid.

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Year:  2009        PMID： 19278246     DOI： 10.1021/ol900262t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

Review 1.  Rearrangements of organic peroxides and related processes.

Authors:  Ivan A Yaremenko; Vera A Vil'; Dmitry V Demchuk; Alexander O Terent'ev
Journal:  Beilstein J Org Chem       Date:  2016-08-03       Impact factor: 2.883

Review 2.  Lewis Acids and Heteropoly Acids in the Synthesis of Organic Peroxides.

Authors:  Ivan A Yaremenko; Peter S Radulov; Yulia Yu Belyakova; Dmitriy I Fomenkov; Svetlana B Tsogoeva; Alexander O Terent'ev
Journal:  Pharmaceuticals (Basel)       Date:  2022-04-13

3.  A new peroxide fragmentation: efficient chemical generation of (1O2) in organic media.

Authors:  Prasanta Ghorai; Patrick H Dussault
Journal:  Org Lett       Date:  2009-10-15       Impact factor: 6.005

4.  Five-Membered Ring Peroxide Selectively Initiates Ferroptosis in Cancer Cells.

Authors:  Rachel P Abrams; William L Carroll; K A Woerpel
Journal:  ACS Chem Biol       Date:  2016-03-01       Impact factor: 5.100

Review 5.  Synthesis of five- and six-membered cyclic organic peroxides: Key transformations into peroxide ring-retaining products.

Authors:  Alexander O Terent'ev; Dmitry A Borisov; Vera A Vil'; Valery M Dembitsky
Journal:  Beilstein J Org Chem       Date:  2014-01-08       Impact factor: 2.883

6.  A H2O2/HBr system - several directions but one choice: oxidation-bromination of secondary alcohols into mono- or dibromo ketones.

Authors:  Gennady I Nikishin; Nadezhda I Kapustina; Liubov L Sokova; Oleg V Bityukov; Alexander O Terent'ev
Journal:  RSC Adv       Date:  2018-08-10       Impact factor: 4.036
  6 in total

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