Literature DB >> 19277390

Activation of hydrocarbon C-H bonds by iodosylbenzene: how does it compare with iron(IV)-oxo oxidants?

Soo Jeong Kim1, Reza Latifi, Hye Yeon Kang, Wonwoo Nam, Sam P de Visser.   

Abstract

Combined experimental and theoretical studies on the reactivity of iodosylbenzene (PhIO) show that PhIO is capable of activating weak C-H bonds of hydrocarbons via a hydrogen abstraction mechanism.

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Year:  2009        PMID： 19277390     DOI： 10.1039/b820812c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates.

Authors:  Apparao Draksharapu; Davide Angelone; Matthew G Quesne; Sandeep K Padamati; Laura Gómez; Ronald Hage; Miquel Costas; Wesley R Browne; Sam P de Visser
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-02-06

2.  Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.

Authors:  Apparao Draksharapu; Davide Angelone; Matthew G Quesne; Sandeep K Padamati; Laura Gómez; Ronald Hage; Miquel Costas; Wesley R Browne; Sam P de Visser
Journal:  Angew Chem Int Ed Engl       Date:  2015-02-06       Impact factor: 15.336

3.  Isolable iodosylarene and iodoxyarene adducts of Co and their O-atom transfer and C-H activation reactivity.

Authors:  Ethan A Hill; Margaret L Kelty; Alexander S Filatov; John S Anderson
Journal:  Chem Sci       Date:  2018-04-23       Impact factor: 9.825
  3 in total

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