| Literature DB >> 19275249 |
Shu-Dan Bian1, Jian-Hua Jia, Quan-Ming Wang.
Abstract
Two high-nuclearity silver clusters have been prepared by reacting AgC(2)Bu(t) with AgBF(4) (or AgOTf) in the presence of TMEDA in air. The reaction takes up atmospheric CO(2) to give CO(3)(2-), which functions as a template for the formation of the cage compounds, whose nuclearities depend on the particular counteranions employed.Entities:
Year: 2009 PMID： 19275249 DOI： 10.1021/ja8087696
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419