Literature DB >> 19271703

Magnesium-magnesium bond stabilized by a doubly reduced alpha-diimine: synthesis and structure of [K(THF)3]2[LMg-MgL] (L = [(2,6-(i)Pr2C6H3)NC(Me)]2(2-)).

Yanyan Liu1, Shaoguang Li, Xiao-Juan Yang, Peiju Yang, Biao Wu.   

Abstract

A new Mg-Mg-bonded compound stabilized by a doubly reduced alpha-diimine ligand, [K(THF)(3)](2)[LMg-MgL] (L = [(2,6-(i)Pr(2)C(6)H(3))NC(Me)](2)(2-)), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) A.

Entities:  

Year:  2009        PMID： 19271703     DOI： 10.1021/ja900568c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  1,4-Bis(4-bromo-2,6-diisopropyl-phen-yl)-1,4-diaza-buta-1,3-diene.

Authors:  Ilia A Guzei; Nicholas J Hill; Matthew R Van Hout
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-12-04

2.  Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.

Authors:  Ross Campbell; Pablo García-Alvarez; Alan R Kennedy; Robert E Mulvey
Journal:  Chemistry       Date:  2010-09-03       Impact factor: 5.236

3.  Many Mg-Mg bonds form the core of the Mg16Cp*8Br4K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?

Authors:  T Kruczyński; F Henke; M Neumaier; K H Bowen; H Schnöckel
Journal:  Chem Sci       Date:  2015-11-26       Impact factor: 9.825

4.  Reductive Dimerization of CO by a Na/Mg(I) Diamide.

Authors:  Han-Ying Liu; Ryan J Schwamm; Samuel E Neale; Michael S Hill; Claire L McMullin; Mary F Mahon
Journal:  J Am Chem Soc       Date:  2021-10-15       Impact factor: 15.419

5.  Electronic and Geometric Structures of Paramagnetic Diazadiene Complexes of Lithium and Sodium.

Authors:  Haleh H Haeri; Ramesh Duraisamy; Nicole Harmgarth; Phil Liebing; Volker Lorenz; Dariush Hinderberger; Frank T Edelmann
Journal:  ChemistryOpen       Date:  2018-09-05       Impact factor: 2.911
  5 in total

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