| Literature DB >> 19259578 |
Fei Cheng1, Andrew L Hector, William Levason, Gillian Reid, Michael Webster, Wenjian Zhang.
Abstract
The trifluorosilicon(iv) cation [SiF(3)(Me(3)tacn)](+), isolated as salts with [SiF(5)](-), [B{3,5-(CF(3))(2)C(6)H(3)}(4)](-) or Cl(-), is obtained by reaction of SiF(4) with Me(3)tacn under anhydrous conditions, and compared with the tetrafluoro complexes [SiF(4)(tmeda)] and [SiF(4){kappa(2)-Me(2)N(CH(2))(2)NMe(CH(2))(2)NMe(2)(CH(2)Cl)}][SiF(5)] obtained with the acyclic di- and tri-amines.Entities:
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Year: 2009 PMID： 19259578 DOI： 10.1039/b822236c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222