Literature DB >> 19257786

Switching Ti valence in SrTiO3 by a dc electric field.

T Leisegang1, H Stöcker, A A Levin, T Weissbach, M Zschornak, E Gutmann, K Rickers, S Gemming, D C Meyer.   

Abstract

A (001) SrTiO3 wafer has been investigated in situ at room temperature under application of a static electric field of varying polarity by fluorescence x-ray absorption near edge structure (XANES) analysis at the Sr-K and Ti-K absorption edges. The XANES spectra show a clear shift of the Ti-K absorption edge energy. The shift is attributed to a change of the Ti valence state in a volume invoked by diffusion of the oxygen ions and vacancies. No shift was observed for the Sr-K absorption edge energy. Theoretical calculations support these findings.

Entities:  

Year:  2009        PMID: 19257786     DOI: 10.1103/PhysRevLett.102.087601

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Ferroelectric-like SrTiO3 surface dipoles probed by graphene.

Authors:  Raymond Sachs; Zhisheng Lin; Jing Shi
Journal:  Sci Rep       Date:  2014-01-13       Impact factor: 4.379

2.  Crystallization dynamics and interface stability of strontium titanate thin films on silicon.

Authors:  Florian Hanzig; Juliane Hanzig; Erik Mehner; Carsten Richter; Jozef Veselý; Hartmut Stöcker; Barbara Abendroth; Mykhaylo Motylenko; Volker Klemm; Dmitri Novikov; Dirk C Meyer
Journal:  J Appl Crystallogr       Date:  2015-03-12       Impact factor: 3.304

  2 in total

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