Literature DB >> 19257755

Probing the equilibrium dynamics of colloidal hard spheres above the mode-coupling glass transition.

G Brambilla1, D El Masri, M Pierno, L Berthier, L Cipelletti, G Petekidis, A B Schofield.   

Abstract

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades in structural relaxation time, tau(alpha0, including equilibrium measurements above phi(c), the location of the glass transition deduced from fitting our data to mode-coupling theory. Instead of falling out of equilibrium, the system remains ergodic above phi(c) and enters a new dynamical regime where tau(alpha) increases with a functional form that was not anticipated by previous experiments, while the amplitude of dynamic heterogeneity grows slower than a power law with tau(alpha), as found in molecular glass formers close to the glass transition.

Year:  2009        PMID: 19257755     DOI: 10.1103/PhysRevLett.102.085703

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  22 in total

1.  Testing "microscopic" theories of glass-forming liquids.

Authors:  L Berthier; G Tarjus
Journal:  Eur Phys J E Soft Matter       Date:  2011-09-23       Impact factor: 1.890

2.  Discontinuous shear thickening in Brownian suspensions by dynamic simulation.

Authors:  Romain Mari; Ryohei Seto; Jeffrey F Morris; Morton M Denn
Journal:  Proc Natl Acad Sci U S A       Date:  2015-11-30       Impact factor: 11.205

3.  Hard sphere-like glass transition in eye lens α-crystallin solutions.

Authors:  Giuseppe Foffi; Gabriela Savin; Saskia Bucciarelli; Nicolas Dorsaz; George M Thurston; Anna Stradner; Peter Schurtenberger
Journal:  Proc Natl Acad Sci U S A       Date:  2014-11-10       Impact factor: 11.205

4.  Bond orientational order in liquids: Towards a unified description of water-like anomalies, liquid-liquid transition, glass transition, and crystallization: Bond orientational order in liquids.

Authors:  Hajime Tanaka
Journal:  Eur Phys J E Soft Matter       Date:  2012-10-31       Impact factor: 1.890

5.  Refractive index matched, nearly hard polymer colloids.

Authors:  Gregory N Smith; Matthew J Derry; James E Hallett; Joseph R Lovett; Oleksander O Mykhaylyk; Thomas J Neal; Sylvain Prévost; Steven P Armes
Journal:  Proc Math Phys Eng Sci       Date:  2019-06-26       Impact factor: 2.704

6.  Configurational entropy measurements in extremely supercooled liquids that break the glass ceiling.

Authors:  Ludovic Berthier; Patrick Charbonneau; Daniele Coslovich; Andrea Ninarello; Misaki Ozawa; Sho Yaida
Journal:  Proc Natl Acad Sci U S A       Date:  2017-10-10       Impact factor: 11.205

7.  Understanding, predicting, and tuning the fragility of vitrimeric polymers.

Authors:  Simone Ciarella; Rutger A Biezemans; Liesbeth M C Janssen
Journal:  Proc Natl Acad Sci U S A       Date:  2019-11-25       Impact factor: 11.205

Review 8.  The Interplay between the Theories of Mode Coupling and of Percolation Transition in Attractive Colloidal Systems.

Authors:  Francesco Mallamace; Giuseppe Mensitieri; Martina Salzano de Luna; Paola Lanzafame; Georgia Papanikolaou; Domenico Mallamace
Journal:  Int J Mol Sci       Date:  2022-05-10       Impact factor: 6.208

9.  On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case.

Authors:  Francesco Mallamace; Carmelo Corsaro; Nancy Leone; Valentina Villari; Norberto Micali; Sow-Hsin Chen
Journal:  Sci Rep       Date:  2014-01-17       Impact factor: 4.379

10.  Discontinuous nature of the repulsive-to-attractive colloidal glass transition.

Authors:  T van de Laar; R Higler; K Schroën; J Sprakel
Journal:  Sci Rep       Date:  2016-03-04       Impact factor: 4.379

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