| Literature DB >> 19256888 |
Prabhat K Gupta1, John C Mauro.
Abstract
We derive an analytical expression showing that the fragility of a supercooled liquid is a result of (i) a thermodynamic term depending on change in configurational entropy and (ii) a kinetic term depending on change in the nonexponentiality or "stretching" of the relaxation function, as quantified by the exponent beta of the Kohlrausch-Williams-Watts (KWW) relaxation function. Our expression indicates that there is not a direct correlation between the non-Arrhenius scaling of liquid viscosity and the nonexponential nature of glassy relaxation. Rather, the temperature dependence of the stretching exponent beta provides a lower limit for fragility, which can be increased through changes in the configurational entropy. Our result explains the apparent contradiction between those researchers showing a correlation between beta and fragility and those who question such a correlation due to the spread of the data.Year: 2008 PMID: 19256888 DOI: 10.1103/PhysRevE.78.062501
Source DB: PubMed Journal: Phys Rev E Stat Nonlin Soft Matter Phys ISSN: 1539-3755