Literature DB >> 19256888

Two factors governing fragility: stretching exponent and configurational entropy.

Prabhat K Gupta1, John C Mauro.   

Abstract

We derive an analytical expression showing that the fragility of a supercooled liquid is a result of (i) a thermodynamic term depending on change in configurational entropy and (ii) a kinetic term depending on change in the nonexponentiality or "stretching" of the relaxation function, as quantified by the exponent beta of the Kohlrausch-Williams-Watts (KWW) relaxation function. Our expression indicates that there is not a direct correlation between the non-Arrhenius scaling of liquid viscosity and the nonexponential nature of glassy relaxation. Rather, the temperature dependence of the stretching exponent beta provides a lower limit for fragility, which can be increased through changes in the configurational entropy. Our result explains the apparent contradiction between those researchers showing a correlation between beta and fragility and those who question such a correlation due to the spread of the data.

Year:  2008        PMID: 19256888     DOI: 10.1103/PhysRevE.78.062501

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  1 in total

1.  Viscosity of glass-forming liquids.

Authors:  John C Mauro; Yuanzheng Yue; Adam J Ellison; Prabhat K Gupta; Douglas C Allan
Journal:  Proc Natl Acad Sci U S A       Date:  2009-11-10       Impact factor: 11.205

  1 in total

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