Literature DB >> 19248062

First higher-order photocycloaddition to a C=N bond: 1,3-diazepines from maleimides.

Kara L Cubbage1, Andrew J Orr-Ewing, Kevin I Booker-Milburn.   

Abstract

A light touch is all that is required to cleave a maleimide C-n class="Chemical">N bond to effect a [5+2] photocycloaddition with a sterically encumbered C=N moiety (see scheme).

Entities:  

Year:  2009        PMID： 19248062     DOI： 10.1002/anie.200805846

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  1 in total

1.  A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation/Ring-Expansion Approach to Substituted Azepanes.

Authors:  Scott M Thullen; David M Rubush; Tomislav Rovis
Journal:  Synlett       Date:  2017-06-29       Impact factor: 2.454
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.