Literature DB >> 19245246

Unexpected de-arylation of a pentaaryl fullerene.

Simon Clavaguera1, Saeed I Khan, Yves Rubin.   

Abstract

A triphenylamine-derived pentaaryl fullerene undergoes an unusual oxidative dearylation under basic conditions to give tetraarylated epoxy fullerene in high yield. The structure of the product was confirmed by single crystal X-ray diffraction. A mechanism is proposed to account for the loss of the addend and the subsequent formation of the epoxide group.

Entities:  

Year:  2009        PMID： 19245246     DOI： 10.1021/ol900224w

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Perfluoroalkylfullerenes.

Authors:  Olga V Boltalina; Alexey A Popov; Igor V Kuvychko; Natalia B Shustova; Steven H Strauss
Journal:  Chem Rev       Date:  2015-01-15       Impact factor: 60.622

2.  Flat-on ambipolar triphenylamine/C60 nano-stacks formed from the self-organization of a pyramid-sphere-shaped amphiphile.

Authors:  Wei-Wei Liang; Chi-Feng Huang; Kuan-Yi Wu; San-Lien Wu; Shu-Ting Chang; Yen-Ju Cheng; Chien-Lung Wang
Journal:  Chem Sci       Date:  2016-01-04       Impact factor: 9.825
  2 in total

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