| Literature DB >> 19235979 |
István Szilágyi1, Erich Königsberger, Peter M May.
Abstract
Ion association in concentrated aqueous solutions of titanyl sulfate in sulfuric acid has been investigated at 25 degrees C by Raman spectroscopy under conditions like those used in the preparation of titania nanoparticles. Systematic variation of titanyl (M), sulfate (L), and hydrogen ion concentrations and a detailed quantitative analysis of the spectra reveal that two weak titanyl sulfato complexes (ML and ML(2)) are formed, with ML predominating. This assignment conflicts with the recent results of Baillon et al. (J. Mol. Liq. 2008, 143, 8-12).Entities:
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Year: 2009 PMID： 19235979 DOI： 10.1021/ic801722r
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165