Literature DB >> 19235937

*NO2-mediated meso-hydroxylation of iron(III) porphyrin.

G J Abhilash1, Jagannath Bhuyan, Pinky Singh, Suman Maji, Kuntal Pal, Sabyasachi Sarkar.   

Abstract

(*)NO(2) generated from (*)NO and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.

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Year:  2009        PMID: 19235937     DOI: 10.1021/ic800864w

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  5 in total

1.  Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase.

Authors:  Melanie A Ehudin; Laura Senft; Alicja Franke; Ivana Ivanović-Burmazović; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2019-06-26       Impact factor: 15.419

2.  One-pot synthesis of meso-alkyl substituted isocorroles: the reaction of a triarylcorrole with Grignard reagent.

Authors:  Sara Nardis; Giuseppe Pomarico; Federica Mandoj; Frank R Fronczek; Kevin M Smith; Roberto Paolesse
Journal:  J Porphyr Phthalocyanines       Date:  2010-08-01       Impact factor: 1.811

3.  The Eponymous Cofactors in Cytochrome P460s from Ammonia-Oxidizing Bacteria Are Iron Porphyrinoids Whose Macrocycles Are Dibasic.

Authors:  Meghan A Smith; Kyle M Lancaster
Journal:  Biochemistry       Date:  2017-12-06       Impact factor: 3.162

4.  A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate.

Authors:  Isaac Garcia-Bosch; Savita K Sharma; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2013-10-22       Impact factor: 15.419

5.  Sulfheme formation during homocysteine S-oxygenation by catalase in cancers and neurodegenerative diseases.

Authors:  Dominique Padovani; Assia Hessani; Francine T Castillo; Géraldine Liot; Mireille Andriamihaja; Annaïg Lan; Camilla Pilati; François Blachier; Suvajit Sen; Erwan Galardon; Isabelle Artaud
Journal:  Nat Commun       Date:  2016-11-16       Impact factor: 14.919

  5 in total

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