Literature DB >> 19229926

Olefin-dependent discrimination between two nonheme HO-FeV=O tautomeric species in catalytic H2O2 epoxidations.

Anna Company1, Yan Feng, Mireia Güell, Xavi Ribas, Josep M Luis, Lawrence Que, Miquel Costas.   

Abstract

Wet oxygenase models: Unprecedented high levels of water incorporation into products (up to 75%) is observed in epoxidation reactions with H(2)O(2) by a bioinspired nonheme iron catalyst. A surprising substrate-dependent incorporation of water is observed, and is proposed to arise from fast equilibrium between two high-valent HO-Fe(V)=O isomeric species exhibiting different reactivity.

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Year:  2009        PMID： 19229926     DOI： 10.1002/chem.200802597

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  12 in total

1.  Iron-oxo complexes: elusive iron(V) species identified.

Authors:  Aidan R McDonald; Lawrence Que
Journal:  Nat Chem       Date:  2011-09-23       Impact factor: 24.427

2.  Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions.

Authors:  Irene Prat; Jennifer S Mathieson; Mireia Güell; Xavi Ribas; Josep M Luis; Leroy Cronin; Miquel Costas
Journal:  Nat Chem       Date:  2011-09-04       Impact factor: 24.427

3.  One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.

Authors:  Katherine M Van Heuvelen; Adam T Fiedler; Xiaopeng Shan; Raymond F De Hont; Katlyn K Meier; Emile L Bominaar; Eckard Münck; Lawrence Que
Journal:  Proc Natl Acad Sci U S A       Date:  2012-07-11       Impact factor: 11.205

4.  Efficient water oxidation catalysts based on readily available iron coordination complexes.

Authors:  Julio Lloret Fillol; Zoel Codolà; Isaac Garcia-Bosch; Laura Gómez; Juan José Pla; Miquel Costas
Journal:  Nat Chem       Date:  2011-09-04       Impact factor: 24.427

5.  Iron-catalyzed asymmetric epoxidation of β,β-disubstituted enones.

Authors:  Yasuhiro Nishikawa; Hisashi Yamamoto
Journal:  J Am Chem Soc       Date:  2011-05-16       Impact factor: 15.419

6.  Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies.

Authors:  Pieter C A Bruijnincx; Inge L C Buurmans; Yuxing Huang; Gergely Juhász; Marta Viciano-Chumillas; Manuel Quesada; Jan Reedijk; Martin Lutz; Anthony L Spek; Eckard Münck; Emile L Bominaar; Robertus J M Klein Gebbink
Journal:  Inorg Chem       Date:  2011-09-08       Impact factor: 5.165

7.  Regulating the Basicity of Metal-Oxido Complexes with a Single Hydrogen Bond and Its Effect on C-H Bond Cleavage.

Authors:  Suman K Barman; Jason R Jones; Chen Sun; Ethan A Hill; Joseph W Ziller; A S Borovik
Journal:  J Am Chem Soc       Date:  2019-07-05       Impact factor: 15.419

Review 8.  Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

Authors:  Giorgio Olivo; Olaf Cussó; Margarida Borrell; Miquel Costas
Journal:  J Biol Inorg Chem       Date:  2017-01-25       Impact factor: 3.358

9.  High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic FeIV=O Complexes.

Authors:  Lawrence Que
Journal:  Bull Jpn Soc Coord Chem       Date:  2013-11

10.  Regioselectivity of substrate hydroxylation versus halogenation by a nonheme iron(IV)-oxo complex: possibility of rearrangement pathways.

Authors:  Matthew G Quesne; Sam P de Visser
Journal:  J Biol Inorg Chem       Date:  2012-05-13       Impact factor: 3.358
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