| Literature DB >> 19229920 |
Sylvestre Bonnet1, Jie Li, Maxime A Siegler, Lars S von Chrzanowski, Anthony L Spek, Gerard van Koten, Robertus J M Klein Gebbink.
Abstract
Feel the pinch! Planar-chiral, cationic, ruthenium-palladium complexes based on eta(6),eta(1)-coordinated ECE' pincer ligands are synthesized as racemic mixtures by reacting ECE'-palladium complexes and [Ru(C(5)R(5))(MeCN)(3)](+) arenophiles (R=H or Me). Chiral resolution of the cationic complexes was achieved by using the chiral counterion [Delta-TRISPHAT](-), and solving the X-ray crystal structure of one diastereoisomer (shown here).Entities:
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Year: 2009 PMID： 19229920 DOI： 10.1002/chem.200900117
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236