Literature DB >> 19225655

Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3.

Alberto Ramos1, Alan J Lough, Douglas W Stephan.   

Abstract

Mono- and bis-phosphinoferrocenes are shown to react as frustrated Lewis pairs (FLPs) to effect nucleophilic aromatic substitution on B(C(6)F(5))(3) and/or activate H(2) to form ferrocenylphosphonium borates.

Entities:  

Year:  2009        PMID： 19225655     DOI： 10.1039/b819525k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Exploring the Reactivity of B-Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System.

Authors:  Jan Schulz; Menyhárt B Sárosi; Evamarie Hey-Hawkins
Journal:  Chemistry       Date:  2022-05-12       Impact factor: 5.020

2.  An electrochemical study of frustrated Lewis pairs: a metal-free route to hydrogen oxidation.

Authors:  Elliot J Lawrence; Vasily S Oganesyan; David L Hughes; Andrew E Ashley; Gregory G Wildgoose
Journal:  J Am Chem Soc       Date:  2014-04-10       Impact factor: 15.419

3.  Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

Authors:  Gabriella Skara; Freija De Vleeschouwer; Paul Geerlings; Frank De Proft; Balazs Pinter
Journal:  Sci Rep       Date:  2017-11-22       Impact factor: 4.379
  3 in total

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