Literature DB >> 19225638

A new chiral shift reagent for the determination of enantiomeric excess and absolute configuration in cyanohydrins.

Lomary S Moon1, Ravinder S Jolly, Yoganjaneyulu Kasetti, Prasad V Bharatam.   

Abstract

Optically active mandelic acid in the presence of dimethylaminopyridine is an excellent chiral shift reagent for the determination of enantiomeric excess and absolute configuration in cyanohydrins.

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Year:  2009        PMID： 19225638     DOI： 10.1039/b817800c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate.

Authors:  Michael North; Marta Omedes-Pujol
Journal:  Beilstein J Org Chem       Date:  2010-11-03       Impact factor: 2.883

2.  A Gallium-based Chiral Solvating Agent Enables the Use of 1H NMR Spectroscopy to Differentiate Chiral Alcohols.

Authors:  Sumin Jang; Hyunwoo Kim
Journal:  iScience       Date:  2019-08-02

3.  Azaheterocyclic diphenylmethanol chiral solvating agents for the NMR chiral discrimination of alpha-substituted carboxylic acids.

Authors:  Gao-Wei Li; Xiao-Juan Wang; Dan-Dan Cui; Yu-Fei Zhang; Rong-Yao Xu; Shuai-Hua Shi; Lan-Tao Liu; Min-Can Wang; Hong-Min Liu; Xin-Xiang Lei
Journal:  RSC Adv       Date:  2020-09-18       Impact factor: 4.036

4.  Chirality sensing of tertiary alcohols by a novel strong hydrogen-bonding donor - selenourea.

Authors:  Guangling Bian; Shiwei Yang; Huayin Huang; Hua Zong; Ling Song; Hongjun Fan; Xiaoqiang Sun
Journal:  Chem Sci       Date:  2015-10-20       Impact factor: 9.825
  4 in total

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