| Literature DB >> 19219887 |
Jia-Qiang Dong1, Henry N C Wong.
Abstract
Piecing it together: The first total synthesis of naturally occurring diterpene pallavicinolide A was achieved. Notable features are highlighted by three key biomimetic transformations: a base-promoted Grob fragmentation, a singlet oxygen oxidation, and an intramolecular Diels-Alder cycloaddition.Entities:
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Year: 2009 PMID： 19219887 DOI： 10.1002/anie.200806335
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336