Literature DB >> 19216551

Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex.

Chidambaram Gunanathan1, Linda J W Shimon, David Milstein.   

Abstract

The crystallographically characterized ruthenium complex RuHCl(A-(i)Pr-PNP)(CO) (1) [A-(i)Pr-PNP = 4,5-bis-(diisopropylphosphinomethyl)acridine], which bears a nonplanar acridine moiety, catalyzes in a neutral medium the transformation of primary alcohols to the corresponding acetals with the liberation of H(2). In the presence of base, complex 1 catalyzes the dehydrogenative coupling of alcohols to form esters. Acetal formation may involve hemiacetal dehydration to form an enol ether followed by alcohol addition to the double bond.

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Year:  2009        PMID： 19216551     DOI： 10.1021/ja808893g

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  A sustainable catalytic pyrrole synthesis.

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Journal:  Nat Chem       Date:  2013-01-20       Impact factor: 24.427

2.  New ligand platforms featuring boron-rich clusters as organomimetic substituents.

Authors:  Alexander M Spokoyny
Journal:  Pure Appl Chem       Date:  2013-05       Impact factor: 2.453

3.  Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

Authors:  Ekambaram Balaraman; Chidambaram Gunanathan; Jing Zhang; Linda J W Shimon; David Milstein
Journal:  Nat Chem       Date:  2011-07-22       Impact factor: 24.427

Review 4.  Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors:  Amit Kumar; Prosenjit Daw; David Milstein
Journal:  Chem Rev       Date:  2021-11-02       Impact factor: 60.622

5.  Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water.

Authors:  Nasim Ganji; Babak Karimi; Sepideh Najafvand-Derikvandi; Hojatollah Vali
Journal:  RSC Adv       Date:  2020-04-03       Impact factor: 3.361

6.  Reaction-activated palladium catalyst for dehydrogenation of substituted cyclohexanones to phenols and H2 without oxidants and hydrogen acceptors.

Authors:  Jingwu Zhang; Qiangqiang Jiang; Dejun Yang; Xiaomei Zhao; Yanli Dong; Renhua Liu
Journal:  Chem Sci       Date:  2015-05-19       Impact factor: 9.825

7.  Transformation of alcohols to esters promoted by hydrogen bonds using oxygen as the oxidant under metal-free conditions.

Authors:  Mingyang Liu; Zhanrong Zhang; Huizhen Liu; Zhenbing Xie; Qingqing Mei; Buxing Han
Journal:  Sci Adv       Date:  2018-10-05       Impact factor: 14.136

8.  Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(ii) catalyst.

Authors:  Junjie Cheng; Meijuan Zhu; Chao Wang; Junjun Li; Xue Jiang; Yawen Wei; Weijun Tang; Dong Xue; Jianliang Xiao
Journal:  Chem Sci       Date:  2016-03-29       Impact factor: 9.825

9.  Additive-Mediated Selective Oxidation of Alcohols to Esters via Synergistic Effect Using Single Cation Cobalt Catalyst Stabilized with Inorganic Ligand.

Authors:  Jingjing Wang; Han Yu; Zheyu Wei; Qi Li; Weimin Xuan; Yongge Wei
Journal:  Research (Wash D C)       Date:  2020-01-23

Review 10.  Sustainable catalysis with fluxional acridine-based PNP pincer complexes.

Authors:  Sayan Kar; David Milstein
Journal:  Chem Commun (Camb)       Date:  2022-03-18       Impact factor: 6.222
  10 in total

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